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Protocol for using [Ph3C][B(C6F5)4] in cationic polymerization The use of [Ph3C][B(C6F5)4] often leads to living or controlled polymerizations, enabling the synthesis of polymers with well-defined molecular weights and narrow molecular weight distributions This document provides detailed protocols for the use of [Ph3C][B(C6F5)4] in the cationic polymerization of representative monomers Data Presentation
Lithium tetrakis (pentafluorophenyl)borate - Wikipedia Lithium tetrakis (pentafluorophenyl)borate is the lithium salt of the weakly coordinating anion (B (C 6 F 5) 4) − Because of its weakly coordinating abilities, lithium tetrakis (pentafluorophenyl)borate makes it commercially valuable in the salt form in the catalyst composition for olefin polymerization reactions and in electrochemistry
Conversion of waste poly (vinyl chloride) to branched . . . Herein, full dechlorination of PVC has been achieved via generation of silylium ions in situ, to furnish PE products Complete dechlorination of PVC can be achieved in 2 hours, yielding organic polymer that has similar spectroscopic and thermal signatures of branched PE, with no observable chlorine
Lithium tetrakis (pentafluorophenyl)borate ethyl etherate In this nano-antenna, the cationic dyes are brought together in very close proximity using bulky Baeyer-Villiger oxidation and oxidative cascade reactions with aqueous hydrogen peroxide catalyzed by lipophilic Li [B (C6F5) 4] and Ca [B (C6F5) 4] 2
[Ph3C] [B (C6F5)4]: A Highly Efficient Metal‐Free Single . . . Abstract Commercially available [Ph3C] [B (C6F5)4] served as a highly efficient metal-free and single-component initiator not only for the carbocationic polymerization of polar and bulky aryl isocyan